02. Influence of fermentation activity of typical chernozem on content and hydrophobic-and-hydrophilic properties of humic acids at different techniques of soil cultivation

https://doi.org/10.31073/agrovisnyk201705-02
Skryl'nyk Je. V., Makliuk O. I., Popirnyj M. A.
Pages: 1116.

Full article: 
Abstract
The purpose. To study influence of fermentation activity of oxide-reductases of typical chernozem on content and hydrophobic-and-hydrophilic properties of humic acids (HA) at different techniques of soil cultivation. Methods. Field, laboratory-analytical, spectrometric. Results. Increase of polyphenoloxidase activity for 10-years use of zero cultivation promotes heightening of hydrophoby of HA due to formation of big quantity of condensed non-polar aromatic structures. After ploughing occurs re-organization of conformation of macrostructure of HA, which is caused by formation of more polar hydrophilous structures of HA in view of changing oxide-reductase activity, that in its turn causes greater moving ability of humus in comparison with zero cultivation and layland. Conclusions. Use of zero cultivation promotes reverse re-organization of functional macrostructure of HA due to change of oxide-reductase activity aside formation of hydrophobic structures – non-polar aromatic compounds.


Key words: oxide-reductase, soil cultivation, humic acids, non-polar aromatic structures, hydrophobic- and-hydrophilic properties, re-organization of conformation.



References
  1. Bayer C. Tillage and cropping system effects on soil humic acid characteristics as determined by electron spin resonance and fluorescence spectroscopies/C. Bayer, L. Martin-Neto, J. Mielniczuk, ´et al//Geoderma.- 2002. N. 105. — P. 81—92.
  2. D. S. Orlov. Humic acid soils and the general theory of humification/D. S. Orlov. - M .: MGU, 1990. - 325 p
  3. Piccolo A. The supramolecular structure of humic substances. A novel understanding of humus chemistry and application in Soil Science./A. Piccolo//Advances in Agronomy. - 2002. - № 75. — P. 57— 133.
  4. Wershaw R. L. Molecular aggregation of humic substances/R. L. Wershaw, L. Robert//Soil Science. - 1999. — № 164. — P. 803—813.
  5. Milanovsky E. Y. Amphihpiles component of humic substances of soil/E. Y Milanovsky//Eurasian Soil Sience. — 2000. - № 6. — P. 706 — 715.
  6. Tsapko Yu. L. Discussion problem of humus nature /Yu. L. Tsapko/Ukr Soil Sci. - 2015.-№ 3-4 .- P. 83-89.
  7. Kravchenko Y. Quality and dynamics of soil organic matter in a typical Chernozem of Ukraine under different long-term tillage systems/Y. Kravchenko, N. Rogovska, L. Petrenko//Canadian Journal of Soil Science. - 2012. — N. 92.-P. 429-438.
  8. Hasiev F. H. Methods of soil enzymes/F. H. Hasiev; M.: Science, 2005.- 252 p.
  9. The quality of the soil. Methods for extraction of humic substances ISO 7606:2014. — [Effective as 29.01.2014]. — K. : State Committee of Ukraine, 2014. — 8 p. — (National standard of Ukraine).
  10. Popirny M. A. Effect of tillage intensity on composition, physical and chemical properties of the second fraction of humic acids extracted from typical chernozem/M. A. Popirny, O. T. Nikolov, E. V. Skrilnik//Biophysics Bulletin of Kharkov national university. — 2016. — N. 35 (10).- P. 34-45
  11. Dormaar J. F. Infrared spectra of humic acids from soils formed under grass or trees/J. F. Dormaar//Geoderma.- 1967. - N. 1.- P. 37-45.